Question #04e6f

1 Answer
Dec 7, 2014

The answer is 0.13 grams.

First, let's start with the balanced equation

Zn(s) + 2HCl(aq) -> ZnCL_2(aq) + H_2(g)

Now, the gas collected in t he 36.6mL tube is hydrogen mixed with water vapor. In order to get the amount of hydrogen (H_2), we must get its partial pressure in the mixture by using Dalton's law.

So, the total pressure collected over the water is equal to the partial pressure of water and the partial pressure of H_2.

P_(coll e c ted) = P_(H_2) + P_(water), which means

P_(H_2) = P_(co l l e c t ed) - P_(water) = 890.0 - 17.5 = 872.5 mmHg.

Using the ideal gas law, PV = nRT, we can determine the number of moles of H_2 produced in the reaction

n_(H_2) = (PV)/(RT) = ((872.5/760) * 36.6 * 10^(-3))/(0.082 * (20 +273.15)) = 0.002 mol es (notice the conversions of pressure, volume and temperature to atm, L, and K, respectively);

From the balanced equation we can see that we have a 1:1 mole ratio between Zn and H_2, which means that the number of moles of Zn is equal to

n_(Zn) = 0.002 moles

Therefore, the mass of Zn (knowing that its molar mass is 65.4 g/(mol)), is equal to

m_(Zn) = n_(Zn) * 65.4 g/(mol) = 0.004 mol es * 65.4 g/(mol) = 0.13 g

Here's a helpful link to better visualize this reaction:

http://employees.oneonta.edu/viningwj/modules/CI_limiting_reactants_zinc_HCl.html