Question #a73d6

2 Answers
Dec 11, 2014

Let us look at the following equations

3NO2 + H2O −→ 2HNO3 + NO.

As per the above equation 3 moles of NO2 are needed to form or get 2 moles of HNO3.

in terms of molar mass , one mole of NO2 has mass 46.0 g and one mole of HNO3 has mass 63.0 g ( approx.)

3 mole of NO2 produces 2 moles of HNO3

46 x 3 g of NO2 produces 2 x 63 g of HNO3

138 g of NO2 produces 126 g of HNO3

To get 1 g of HNO3 we will need ( 138g / 126g ) of NO2

To get 1 g of HNO3 we will need 1.10g of NO2

To get 63.0 g of HNO3 we will need 63 x 1.10 g of NO2

69.3 g of NO2

Dec 11, 2014

The answer is 83g.

Starting from the balanced chemical equation

3NO2+H2O2HNO3+NO

one can see that we have a 3:2 mole ratio between NO2 and H2O; that is, for every 3 moles of NO2 that react, 2 moles of HNO3 are formed.

Now, starting from the given mass of nitric acid, mHNO3=75g, one can determine the number of moles formed in the reaction and, by working backwards, determine how many moles of NO2 were used. So,

nHNO3=massHNO3molarmass=75g63gmol=1.2 moles (knowing that nitric acid's molar mass is 63gmol).

Therefore, the number of NO2 moles used is

nNO2=321.2=1.8 moles

Using the same conversion between moles and mass, one can determine that

mNO2=1.8moles46gmol=83g (NO2's molar mass is 46gmol).