"5.25 g" of "NaF" will be produced (or "5 g" if you round to 1 sig fig - the number of sig figs 0.5 has).
So, you have your balanced chemical equation, which I won't write again here. Notice that you have an "8:2", or better said, a "4:1" mole ratio between "HF" and "NaF".
This means that "4 moles" of "HF" will produce "1 mole" of "NaF". Since you were given the number of "HF" moles, and told that Na_2SiO_3 was not a limiting reagent, you can determine the number of "NaF" moles to be
"0.5 moles HF" * ("1 mole NaF")/("4 moles HF") = "0.125 moles"
"NaF" has a molar mass of "42.0 g/mol", which means that the mass produced will be
"0.125 moles" * ("42.0 g")/("1 mole") = "5.25 g NaF"