The thimble contains 3.3 * 10^(-4)3.3⋅10−4 moles of water.
To go from number of molecules to moles and vice versa, you can use Avogadro's number, which describes the number of atoms or molecules present in a mole of substance.
According to this, each mole contains exactly 6.022 * 10^(23)6.022⋅1023 atoms or molecules; in your case, 1 mole of water would contain 6.022 * 10^(23)6.022⋅1023 molecules of water.
Since 2.0 * 10^(20)2.0⋅1020 is a smaller number than 6.022 * 10^(23)6.022⋅1023, you'll have less than 1 mole of water in a thimble.