Question #cf988

1 Answer
Jan 13, 2016

DeltaH = +"12.2 kJ"

Explanation:

Yes, you are correct.

The molar enthalpy of vaporization, or simply the enthalpy of vaporization, tells you the enthalpy change that occurs when one mole of a substance goes from liquid at its boiling point to vapor at its boiling point.

Since heat is needed in order for a substance to undergo a liquid -> vapor phase change, the enthalpy of vaporization, DeltaH_"vap", will carry a positive sign.

In your case, the value

DeltaH_"vap" = + "39.23 kJ/mol"

tells you that "39.23 kJ" of heat are being given off when one mole of methanol undergoes a liquid -> vapor phase change.

Convert the mass of methanol to moles by using the compound's molar mass

10.0 color(red)(cancel(color(black)("g"))) * ("1 mole CH"_3"OH")/(32.04color(red)(cancel(color(black)("g")))) = "0.3121 moles CH"_3"OH"

So, if one mole gives off "39.23 kJ" of heat, it follows that 0.3121 moles will give off

0.3121 color(red)(cancel(color(black)("moles CH"_3"OH"))) * "39.23 kJ"/(1color(red)(cancel(color(black)("mole CH"_3"OH")))) = "12.24 kJ"

The enthalpy change will thus be

DeltaH = color(green)(+"12.2 kJ")

The answer is rounded to three sig figs.