Why do boiling points differ between materials?

1 Answer
Jan 8, 2018

Because different liquids have different degrees of intermolecular force?

Explanation:

Let us take 2 common liquids: "(i) water; and (ii) diethyl ether...."(i) water; and (ii) diethyl ether....

At 34.634.6 ""^@CC, water has a vapour pressure of 41.1*mm*Hg41.1mmHg...but at this temperature, diethyl ether has a vapour pressure of 760*mm*Hg760mmHg. How did I know the latter? Because I know that at the "normal boiling point"normal boiling point, the vapour pressure of the liquid is 1*atm-=760*mm*Hg1atm760mmHg. (How did I know the former? Well, I have got a handy table in front of me that tells me the vapour pressure of water at various temperatures.)

So a question for you to consider, what is the vapour pressure of water at 100100 ""^@CC?