Let us take 2 common liquids: "(i) water; and (ii) diethyl ether...."(i) water; and (ii) diethyl ether....
At 34.634.6 ""^@C∘C, water has a vapour pressure of 41.1*mm*Hg41.1⋅mm⋅Hg...but at this temperature, diethyl ether has a vapour pressure of 760*mm*Hg760⋅mm⋅Hg. How did I know the latter? Because I know that at the "normal boiling point"normal boiling point, the vapour pressure of the liquid is 1*atm-=760*mm*Hg1⋅atm≡760⋅mm⋅Hg. (How did I know the former? Well, I have got a handy table in front of me that tells me the vapour pressure of water at various temperatures.)
So a question for you to consider, what is the vapour pressure of water at 100100 ""^@C∘C?