Question #50ff0

1 Answer
May 4, 2016

"8.3 g"

Explanation:

You can use Parts Per Million, or ppm, to express the concentration of solutions that contain very, very small amounts, often called trace amounts, of solute.

More specifically, a concentration of "1 ppm" is equivalent to one part solute for every 10^6 parts of solvent. One way to express ppm concentration is to use the mass of solute in grams and the mass of solvent in grams

color(blue)(|bar(ul(color(white)(a/a)"ppm" = "grams of solute"/"grams of solvent" xx 10^6color(white)(a/a)|)))

This basically tells you that a concentration of "1 ppm" will contain "1 g" of solute for every 10^6"g" of solvent.

Since you can safely assume that the mass of the solvent is equal to that of the solution, you can say that a con concentration of "6 ppm" will contain "6 g" of solute in 10^6"g" of solution.

Now, the problem tells you this solution contains "0.050 mg" of solute, which is equivalent to

0.050 color(red)(cancel(color(black)("mg solute"))) * "1 g"/(10^3color(red)(cancel(color(black)("mg solute")))) = 5.0 * 10^(-5)"g"

Now all you have to do is use the "6 ppm" concentration as a conversion factor to determine how many grams of solution would contain this many grams of solvent

5.0 * 10^(-5)color(red)(cancel(color(black)("g solute"))) * overbrace((10^6"g solution")/(6color(red)(cancel(color(black)("g solute")))))^(color(purple)("= 6 ppm")) = color(green)(|bar(ul(color(white)(a/a)"8.3 g solution"color(white)(a/a)|)))

I'll leave the answer rounded to two sig figs.

One interesting thing to notice here is that you can write a concentration of "1 ppm" as

"1 g solute"/(10^6"g solution") = (1 * color(red)(cancel(color(black)(10^(3))))"mg solute")/(1 * color(red)(cancel(color(black)(10^(6)))) * color(red)(cancel(color(black)(10^(-3))))"kg solution") = "1 mg solute"/"1 kg solution"

So, if "1 ppm" is equivalent to "1 mg" of solute in "1 kg" of solution, you can say that "6 ppm" will be equivalent to "6 mg" of solute in "1 kg" of solution.

Therefore,

0.050 color(red)(cancel(color(black)("mg solute"))) * overbrace("1 kg solution"/(6color(red)(cancel(color(black)("mg solute")))))^(color(purple)("= 6 ppm")) = "0.0083 kg solution"

This will once again be

0.0083 color(red)(cancel(color(black)("kg"))) * (10^3"g")/(1color(red)(cancel(color(black)("kg")))) = color(green)(|bar(ul(color(white)(a/a)"8.3 g solution"color(white)(a/a)|)))