How would we expect the autoprotolysis reaction of water.... 2H2O(l)H3O++HO .... to evolve with increasing temperature?

2 Answers
Dec 13, 2016

Consider the acid base equilibrium in water.......

Explanation:

2H2OH3O++HO

At 298K, under standard conditions, Kw=1014. This is well-known.

The equilibrium reaction is clearly a BOND-BREAKING reaction, and given the extent of reaction (as revealed by Kw) it is thermodynamically uphill. At higher temperatures, we would thus expect the equilibrium to shift to the right, inasmuch as we are supplying some of the energy to break the strong OH bonds.

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Jan 14, 2017

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