By definition, 40.1*g40.1⋅g of calcium atoms contains "Avogadro's number of molecules"Avogadro's number of molecules. We specify this quantity as 1*mol1⋅mol of "calcium atoms"calcium atoms.
And so we take the quotient, (169*g)/(40.1*g*mol^-1)169⋅g40.1⋅g⋅mol−1, and multiply this by N_A, "Avogadro's number of molecules",NA,Avogadro's number of molecules, where N_A=6.022xx10^23*mol^-1NA=6.022×1023⋅mol−1.
And thus the product, (169*cancelg)/(40.1*cancelg*cancel(mol^-1))xx6.022xx10^23*cancel(mol^-1) gives a DIMENSIONLESS number as required, approx. 4xxN_A.
If I asked how many eggs were in 3 dozen eggses, I think you would immediately be able to reply. The question here is much the same sort of question, and can be viewed in the same simple light.