Both of them are different things.
The average kinetic energy is simply the mean kinetic energy a molecule possesses.
From equipartition theorem, this is given to be,
E = (fk_BT)/2
Where f is number of degrees of freedom of the molecule, k_B is the Boltzmann constant, and T is the absolute temperature.
On the other hand, if out of a total N molecules in a system, n_1 Molecules have a velocity v_1, n_2 molecules have a velocity v_2 and so on, then the mean velocity or average velocity is defined to be,
v_(mean) = (n_1v_1 + n_2v_2 + ....)/(n_1 + n_2 + ....)
implies v_(mean) = (sum n_iv_i)/N
Where, N = sum n_i is the total number of molecules in the system.