What is "activated benzene"?

1 Answer
Jun 5, 2017

I am guessing at what you mean.............

Explanation:

But activated benzene would be a benzene substituted by groups that would make the benzene more reactive than C_6H_6 in electrophilic aromatic substitution reactions...........

For example, the reaction of benzene with bromine to give bromobenzene is relatively sluggish:

C_6H_6 + Br_2 stackrel("Fe(II) salt")rarrC_6H_5Br+HBr

And usually some Lewis-acid catalysis is added in the form of a ferrous or ferric salt.

On the other hand, the reaction with a benzene substituted by an activating group, say -OH, -NH_2, would activate the aryl ring towards electrophilic substitution, in fact so much so that di- and trisubstitution would be observed even in the absence of catalysis.

C_6H_5OHstackrel(Br_2)rarrC_6H_4BrOH + C_6H_3Br_2OH

The aryl ring is thus "activated" towards substitution by electrophiles.