What are differences between "Mohr's salt", and "green vitriol"?

1 Answer
Apr 19, 2017

Well, "green vitriol" is Fe(SO)_4, an iron(II) salt.........

Explanation:

And "Mohr's salt" is (NH_4)_2[Fe(SO_4)_2] *6H_2O.

And so in the solid state, they are different formulations.......and have different coordination geometry.

In solution, however, for both species, we LIKELY have [Fe(OH_2)_6]^(2+) as the dominant iron species in solution. The sulfate and ammonium counterions are along for the ride. There is possibly some literature on this, which is likely informed by "UV-vis spectrometry".