How do we identify a strong acid in aqueous solution?

1 Answer
May 18, 2017

As you are no doubt aware, this distinction is usually used in the context of acid/base chemistry.

Explanation:

A strong acid is completely ionized in aqueous solution; viz. for the hydrohalic acids, HX(XF):

HX+H2O(l)H3O++X

The strength of an acid depends upon the completion of this equilibrium; i.e. how far the equilibrium to the right. HI, HBr, and HCl ARE STRONG ACIDS by this criterion, because dissociation/ionization are almost complete.

On the other hand, weaker acids, incompletely ionize:

HF(aq)+H2OH3O++F

This equilibrium lies to the left as we face it due to (i) the intrinsic strength of the HF; and (ii) to the unfavourable entropy effect of the solvated F conjugate base.

For H2SO4 BOTH conjugate bases are stabilized, and this acts as a diacid in water:

H2SO4(aq)+H2O(l)HSO4+H3O+

HSO4+H2O(l)SO24+H3O+