What is the concentration of a 7.8xx10^-9*mol*L^-17.8×109molL1 solution of chloroacetic acid in "parts per billion"parts per billion, i.e. mug*L^-1μgL1?

2 Answers
Jun 28, 2017

Approx.......0.74*mug*L^-10.74μgL1 with respect to "chloroacetic acid......"chloroacetic acid......

Explanation:

7.87.8 "nanomoles per litre"nanomoles per litre == 7.8xx10^-9*mol*L^-17.8×109molL1.

=94.9*g*mol^-1xx7.8xx10^-9*mol*L^-1=94.9gmol1×7.8×109molL1

=7.40xx10^-7*g*L^-1=7.40×107gL1

=7.40xx10^-7*g*L^-1xx10^6*mug*g^-1=7.40×107gL1×106μgg1

=0.74xxmug*L^-1.......

Jun 28, 2017

0.74 mu"g L"^(-1)

Explanation:

The idea here is that you need to convert the number of nanomoles of chloroacetic acid, or monochloroacetic acid (MCA), to micrograms by using the molar mass of the acid.

The problem provides you with the chemical formula of MCA, so grab a Periodic Table and calculate its molar mass.

You know that 1 mole of MCA contains

  • two moles of carbon, 2 xx "C"
  • two moles of oxygen, 2 xx "O"
  • three moles of hydrogen, 3 xx "H"
  • one mole of chlorine, 1 xx "Cl"

To find the molar mass of the acid, simply add the molar masses of all the atoms that make up the compound.

You should end up with

2 * "12.011 g mol"^(-1) + 2 * "15.994 g mol"^(-1) + 3 * "1.00794 g mol"^(-1) + 1 * "35.453 g mol"^(-1)

= "94.4976 g mol"^(-1)

So, you know that 1 mole of MCA has a mass of "94.4976 g" and that

"1 mole" = 10^9 "nanomoles"

This means that 7.8 nanomoles will have a mass of

7.8 color(red)(cancel(color(black)("nanomoles MCA"))) * (1color(red)(cancel(color(black)("mole"))))/(10^9color(red)(cancel(color(black)("nanomoles")))) * "94.4976 g"/(1color(red)(cancel(color(black)("mole MCA"))))

= 737.08 * 10^(-9) "g"

So, you know that

"7.8 nanomoles L"^(-1) = 737.08 * 10^(-9) "g L"^(-1)

and that

"1 g" = 10^6 mu"g"

so you can say that the concentration of the acid expressed in micrograms per liter will be equal to

737.08 * 10^(-9) color(red)(cancel(color(black)("g")))"L"^(-1) * (10^6color(white)(.)mu"g")/(1color(red)(cancel(color(black)("g")))) = color(darkgreen)(ul(color(black)(0.74color(white)(.)mu"g L"^(-1))))

The answer is rounded to two sig figs, the number of sig figs you have for the given concentration.