One mole of atoms equals 6.022xx10^236.022×1023 atoms.
The formula for methane, "CH"_4"CH4 indicates that one mole of the compound contains four moles of hydrogen atoms.
In order to determine how many hydrogen atoms there are in the given moles of methane, multiply the given moles by the mole ratio between "CH"_4"CH4 and "H"H to get moles of "H"H. Then multiply the moles "H"H by "6.022xx10^236.022×1023 atoms/mol.
4.2color(red)cancel(color(black)("mol CH"_4))xx(4"mol H")/(1color(red)cancel(color(black)("mol CH"_4)))="16.8 mol H"
16.8color(red)cancel(color(black)("mol H"))xx(6.022xx10^23"atoms H")/(1color(red)cancel(color(black)("mol H")))=1.0xx10^25" atoms H"
(rounded to two sig figs due to 4.2 mol "CH"_4")