Firstly recall that;
1000ml = 1L
(Na = 23, color(white)(x) O = 16, color(white)(x) S = 32)
Molarity = "Moles of solute"/"Volume of Solvent or Solution"
"Moles of solute" = "Mass of solute"/"Molar mass of solute"
"Volume of solvent" = 1000ml = 1L
"Solute" = Na_2SO_4
"Mass of solute" = 142g
"Molar mass of solute" = (23 xx 2) + 32 + (16 xx 4) gmol^-1
color (white) (XXXXXXXXXX) = 46 + 32 + 64 gmol^-1
color (white) (XXXXXXXXXX) = 142 gmol^-1
rArr "Moles of solute" = (142cancelg)/(142 cancelgmol^-1)
rArr "Moles of solute" = 1mol
rArr Molarity = "Moles of solute"/"Volume of Solvent or Solution"
rArr Molarity = (1 mol)/(1 L)
rArr Molarity = 1 mol L^-1