A 0.967*g mass of an oxide of phosphorus contains 0.422*g of phosphorus. What is its empirical formula?

1 Answer
Sep 11, 2017

We gots P_2O_5.....

Explanation:

We calculate the empirical formula....

"Moles of phosphorus"=(0.422*g)/(30.9737*g*mol^-1)=0.01361*mol

"Moles of oxygen"=(0.967*g-0.422*g)/(15.999*g*mol^-1)=0.0341*mol

We divide thru by the SMALLEST MOLAR quantity to give an empirical formula of P_((0.01361)/(0.01361))O_((0.0341)/(0.01361))

-=PO_(2.50)....

Now the empirical formula is by definition the simplest WHOLE number ratio, so we double the trial formula to give.....

P_2O_5

The actual molecule is P_4O_10 but we would need further data to assess this.