Do chlorates decompose when heated?

1 Answer
Sep 17, 2015

Yes.

Explanation:

Chlorates are ionic compounds that contain the chlorate anion, "ClO"_3^(-)ClO3, and the cation of a metal.

When heated, these compounds undergo decomposition to form oxygen gas, "O"_2O2, and a metal chloride.

The classic example is the decomposition of potassium chlorate, "KClO"_3KClO3, to oxygen gas and potassium chloride, KCl"KCl.

"KClO"_text(3(s]) -> "KCl"_text((s]) + "O"_text(2(g]) uarrKClO3(s]KCl(s]+O2(g]

If you want a general form balanced equation for the decomposition of a metal chlorate, you can use "M"M to denote the metal cation

"MClO"_text(3(s]) -> "MCl"_text((s]) + "O"_text(2(g]) uarrMClO3(s]MCl(s]+O2(g]

Remember to balance this general equation according to the charge of the metal cation. For example, calcium chlorate, "Ca"("ClO"_3)_2Ca(ClO3)2, will decompose to give

"Ca"("ClO"_3)_text(2(s]) -> "CaCl"""_text(2(s]) + 3"O"_text(2(g]) uarrCa(ClO3)2(s]CaCl2(s]+3O2(g]

Here's a video showing the decomposition of potassium chlorate