Does CO2 have a polar bond?

1 Answer
Jul 3, 2018

My word....

Explanation:

Carbon is LESS electronegative than oxygen, and the oxygen atoms polarize electron density towards themselves, thus denuding the carbon atom of electron density...

i.e. δO=δ+C=δO

...and charge separation betokens polarity... But because carbon dioxide is a symmetric molecule...the individual dipoles add in a vector fashion to give a non-polar molecule...

The central carbon atom is reactive towards nucleophiles..pouring a Grignard reagent onto dry ice is the classic way to make a carboxylate salt...extending the carbon chain by ONE....

R+MgCl+CO2(s)dry ether−−−RCO2+MgCl