Here's how you'd go about doing this:
You know that molarity is defined as the number of moles of solute divided by the total volume of the solution. Let's try and do this intuitively first.
If you want to make 1 L of 0.085 M potassium dichromate solution, you need to add 0.085 moles of K_2Cr_2O_7K2Cr2O7 to enough water to make 1 L of solution. This will give you
C= n/V = ("0.085 moles")/("1 L") = 0.085C=nV=0.085 moles1 L=0.085 "M"M
Now, since you are dealing with 0.250 L, which is "1/4th"1/4th of a liter, you'd need 4 times less moles of K_2Cr_2O_7K2Cr2O7 in order to keep the molarity unchanged. So, even without using the formula, you'd have an idea on how much K_2Cr_2O_7K2Cr2O7 to use.
Using the formula will give you
C = n/V = n/("0.250 L") = 0.085C=nV=n0.250 L=0.085 "M"M
n = 0.085M * 0.250L = 0.021n=0.085M⋅0.250L=0.021 "moles"moles
Knowing that K_2Cr_2O_7K2Cr2O7 has a molar mass of "294.2 g/mol"294.2 g/mol, the mass you'd need for this solution will be
m_(K_2Cr_2O_7) = 0.021mK2Cr2O7=0.021 "moles" * 294.2 g/(mol) = 6.18moles⋅294.2gmol=6.18 "g"g.
So, adding 6.18 g of potassium dichromate to enough water to make 0.250L will get a 0.085 M solution.