Among angles that are rational multiples of piπ or 360^circ360∘ there aren't too many that have rational trig functions. In the first quadrant, besides 0^circ0∘ and 90^circ,90∘, there's sin 30^circsin30∘, tan 45^circtan45∘ and cos 60^circcos60∘.
So we're certain the inverse sine of 1/616 is not rational. When we talk about an exact value we're willing to accept an irrational expression, integers composed via addition, subtraction, multiplication, division and root taking. That would generally mean it's the root of a low degree polynomial, which isn't the case here.
We can of course write down an infinite sum and call that the exact value. That doesn't seem right to me.