Since tan(x)=sin(x)/cos(x), we must find sin(sin^{-1}(2/3)) and cos(sin^{-1}(2/3)). Clearly, sin(sin^{-1}(2/3))=2/3 by the definition of an inverse function (in this case, to be more precise, sin(sin^{-1}(x))=x for all -1\leq x\leq 1). Also, the cosine of the "angle" sin^{-1}(2/3) is positive, therefore by the Pythagorean identity, cos(sin^{-1}(2/3))=sqrt{1-sin^{2}(sin^{-1}(2/3))}
=sqrt{1-(2/3)^2}=sqrt{5/9}=sqrt{5}/3.
(You could also draw a right triangle, label one of the angles sin^{-1}(2/3), label the side lengths appropriately, use the Pythagorean theorem and SOH, CAH, TOA appropriately to do this last calculation.)
Therefore, tan(sin^[-1}(2/3))=(2/3)/(sqrt{5}/3)=2/sqrt{5}=(2sqrt{5})/5