Let's consider the right triangle with angle x where cos(x) = sqrt(5)/6
Then cos^(-1)(sqrt(5)/6) = x and so
sin(cos^(-1)(sqrt(5)/6)) = sin(x) = y/6
By the Pythagorean theorem,
(sqrt(5))^2 + y^2 = 6^2 => y = sqrt(36 - 5) = sqrt(31)
So we have one value of sin(cos^(-1)(sqrt(5)/6)) as sqrt(31)/6
But assuming we are looking at cos^(-1) as multivalued, looking at it geometrically loses one solution, as we only look at one possibility for cos^(-1)(sqrt(5)/6). To get the other, note that as as the cosine function is even,
cos(-x) = cos(x) = sqrt(5)/6
So we need to consider -x as our other value. Then, as the sine function is odd,
sin(-x) = -sin(x) = -sqrt(31)/6
Thus the two exact values of sin(cos^(-1)(sqrt(5)/6)) are sqrt(31)/6 and -sqrt(31)/6