How does SO4 have a charge of 2-?

1 Answer
Jul 3, 2016

We are agreed that sulfate anion derives from H2SO4, sulfuric acid, or from sodium sulfate, Na2SO4, which are both manifestly neutral entities.

Explanation:

A typical (if outdated) Lewis structure of sulfuric acid is:

(HO)2S(=O)2

This Lewis structure is equivalent to:

(HO)2S2+(O)2

For a neutral chalcogen atom (chalcogen = S or O), there must be 6 valence electrons. In the representation (HO)2S(=O)2 there are certainly 6 electrons associated with each sulfur or oxygen. Lone pairs are owned by the atom, and thus on neutral oxygen there are 2 electrons from the double bond, and 4 electrons in the lone pairs).

Now of course both H2SO4 and HSO4 are strong acids, and undergoes almost complete ionization in water:

H2SO4(aq)+2H2O(l)SO24+2H3O+

Conservation of charge demands that the sulfate ion has 2 formal negative charges.

Nitric acid has an even more problematic representation: (O=)N+(O)(OH), where there is formal charge separation in even the neutral acid (6 electrons around nitrogen rather than 7; 9 electrons around oxygen rather than 8 ).

See here for another example that assigns formal charge.