What can primary alcohols be oxidized into?

1 Answer
May 2, 2016

TO aldehydes, then to carboxylic acids, and then of course to carbon dioxide.

Explanation:

RCH_2OH + 1/2O_2 rarr RC(=O)H + H_2O

RC(=O)H + 1/2O_2(g) rarr RC(=O)OH

Look at the individual oxidation states of the ipso carbon:
RCH_2OH, -I; RC(=O)H, +I; RC(=O)OH, +III; CO_2, +IV.

I doubt that you would actually have to learn these oxidation states. I include it as a demonstration of the redox manifold of the carbon atom; of course, C in methane CH_4 has an oxidation state of -IV. And C in ethylene, H_2C=CH_2 has an oxidation state of -II...often we speak of oxidation of an olefin, or reduction to ethane, i.e. C(-III)...