What does K_(eq) << 1 mean?

1 Answer
Jul 9, 2016

That the equilibrium favours the reactant side.

Explanation:

For the reaction,

A+BrightleftharpoonsC+D

There is a rate forward, K_f[A][B], and a rate backward, K_r[C][D]

When "rate forward"="rate backward", this is by definition the very condition of chemical equilibrium, which is characterized by an equilibrium constant, K_"eq".

K_"eq"=([C][D])/([A][B]) = K_"f"/K_"r"

And thus, when K_"eq" is small, it means that at equilibrium the reverse rate is much greater than the forward rate, and that the equilibrium favours the reactant side.