What does the R stand for in functional groups?

1 Answer
Feb 1, 2016

When we are not referring to optical isomerism, R in a formula refers to an alkyl residue, C_nH_(2n+1).

Explanation:

When we write RC(=O)H or RCH=CHR, or R_3C-X, clearly we highlight the functional group of interest: aldehyde; olefin; halide etc. Why do we do this? Well, because the interesting chemistry is going to occur at that functional group.

The R substituent, of general formula C_nH_(2n+1) is along for the ride, and is tacked on to the end of the chain.