What is a combination of four quantum numbers that could be assigned to an electron occupying a 5p orbital?

1 Answer
Dec 24, 2015

#n=5, l=1, m_l = -1, m_s = +1/2#

Explanation:

As you know, four quantum numbers are used to describe the position and spin of an electron inside an atom. These four quantum numbers are

![figures.boundless.com](useruploads.socratic.org)

So, you know that you must find a valid combination of quantum numbers that can describe the position and spin of an electron located in a 5p-orbital.

In your case, the principal quantum number, #n#, which tells you on which energy level the electron resides, will be equal to #5#, since a 5p-orbital is located on the fifth energy level.

As you an see, the angular momentum quantum number, #l#, which tells you on which subshell the electron resides, can take values ranging from #0# to #n-1#, with

  • #l=0 -># describing the s-subshell**
  • #l=1 -># describing the p-subshell**
  • #l=2 -># describing the d-subshell**

and so on. IN your case, you need #l# to describe the p-subshell, since a 5p-orbital is located in the 5p-subshell, i.e. the p-subshell located on the fifth energy level. Therefore, you can say that #l=1#.

The magnetic quantum number, #m_l#, which specifies the exact orbital in which you can find the electron, can only take #3# possible values for an electron located in the p-subshell

  • #m_l = -1 -># describes the #p_x# orbital
  • #m_l = color(white)(-)0 -># describes the #p_y# orbital
  • #m_l = +1 -># describes the #p_z# orbital

In your case, all three values for #m_l# are possible.

Finally, the spin magnetic quantum number, #m_s#, can only take two possible values

  • #m_s = +1/2 -># spin-up electron
  • #m_s = -1/2 -># spin-down electron

Both values for #m_s# are possible for your electron. This means that a total of six sets can describe an electron located in a 5p-orbital.

I'll give you two such sets, and leave the other four to you as practice

#n=5, l=1, m_l = -1, m_s = +1/2#

This electron is located on the fifth energy level, in the 5p-subshell, in the #5p_x# orbital, and has spin-up.

#n=5, l=1, m_l = +1, m_s = -1/2#

This electron is located on the fifth energy level, in the 5p-subshell, in the #5p_z# orbital, and has spin-down.