First note that (2/3)^x-9 is well defined for any Real value of x. So the domain is the whole of RR, i.e. (-oo, oo)
Since 0 < 2/3 < 1, the function (2/3)^x is an exponentially decreasing function which takes large positive values when x is large and negative, and is asymptotic to 0 for large positive values of x.
In limit notation, we can write:
lim_(x->-oo) (2/3)^x = -oo
lim_(x->oo) (2/3)^x = 0
(2/3)^x is continuous and strictly monotonically decreasing, so its range is (0, oo).
Subtract 9 to find that the range of (2/3)^x is (-9, oo).
Let:
y = (2/3)^x-9
Then:
y+9 = (2/3)^x
If y > -9 then we can take logs of both sides to find:
log(y+9) = log((2/3)^x) = x log(2/3)
and hence:
x = log(y+9)/log(2/3)
So for any y in (-9, oo) we can find a corresponding x such that:
(2/3)^x-9 = y
That confirms that the range is the whole of (-9, oo).