Which has a stronger polarising force Li^+ or Be^(2+)?

1 Answer
May 20, 2017

Which cation is (i) smaller; and (ii) which has the higher nuclear charge?

Explanation:

And of course the answer is Be^(2+) on both counts. And thus we predict that Be^(2+) is the stronger polarizer. I have no data with respect to Be-C or Li-C bond lengths. Dialkyl berylliums, the which would be fiendishly reactive, would tend to be more molecular than lithium alkyls, which are oligomeric.