Why is phenolphthalein a good indicator for acid-base titrations?

2 Answers
Nov 16, 2017

The phenolphthalein will change colour .

Explanation:

As NaOH (Sodium hydroxide) is a alkaline substance so,it changes colour from colourless to PINK .

Nov 16, 2017

The equation is #"HIn" + "NaOH" → "In"^"-" + "H"_2"O"#.

Explanation:

Phenolphthalein is a weak acid that has different colours in its acid and base forms.

I have indicated the acidic proton by a red arrow.

HPh
(Adapted from slideplayer.com)

Because it is an indicator, we often write its equilibrium as

#underbrace("HIn")_color(red)("colourless") + "H"_2"O" ⇌ underbrace("In"^"-")_color(red)("deep pink") + "H"_3"O"^"+"#

#"p"K_text(a) = 9.7#, so it is 50 % ionized (pink) at pH 9.7.

That's why it is an excellent indicator for strong acid-strong base titrations.

www.titrations.info

The reaction with #"NaOH"# is

#"HIn + NaOH" → "In"^"-" + "H"_2"O"#.