Question #7b377

1 Answer
Nov 23, 2017

Make it clear what kind of concentration you are going to calculate.

Explanation:

There are variety of concentration. First, you must be clear what kind of concentration you want to find.
https://en.wikipedia.org/wiki/Concentration

If you want to calculate mass concentration, divide the mass of the solute m by the volume of solution V.

ρ=m/V

Your answer is wrong because you used the volume of solvent instead of solution.
Dissolving 60 g NaOH in 100 ml water, the volume of the solution will be so different from 100 ml.

Instead, you can calculate mass fraction.
100 ml of water is 100 g and the mass of solution is 60+100=160 g.
Mass fraction of NaOH in this solution is w="mass of solute"/"mass of solution"=60/160=0.375, or 37.5%.

[Some evaluation]
Acording to CRC databook, the density of NaOH solution with mass fraction 0.360 and 0.380 is 1.3900 and 1.4101 respectively. (g/ml) Data are cited from http://www.edu.utsunomiya-u.ac.jp/chem/v8n1/ashida1/TabC05.htm.

Density of this NaOH solution (w=0.375) will be about 1.4051(linear interpolation is applied).

The volume of the solution is about (160 g)/(1.4051 g/(mL))=113.87 (mL) and
the mass concentration is about (60(g))/(0.11387(L))=526.91 (g/L).