A 1.00 L flask contains nitrogen gas. what is the final partial pressure?

A 1.00 L container contains nitrogen gas at 300k and a pressure of 2.3 atm. 0.30 mol of O2(g) is added to the flask and allowed to mix. Then a lid is opened to allow 0.040 moles of molecules to leave.
What is the partial pressure of oxygen in the final mixture?

2 Answers
Jun 16, 2018

"6 atm"6 atm.

Explanation:

To answer this question, we'll need to use two formulas:

  • The ideal gas law, or pV = nRTpV=nRT.
  • An expression of Dalton's law of partial pressures, or
    P_a = x_a xx P_"total"Pa=xa×Ptotal,
    where aa is a gas and x_axa is the mole fraction of that gas.

First, let's use the ideal gas law to find the number of moles of nitrogen in the container! :)

The question tells us that the N_2N2 gas is at "300 K"300 K, "2.3 atm"2.3 atm, and stored in a "1.00 L"1.00 L container.
So, we'll just plug these values into the equation, using "0.08206 L atm/K mol"0.08206 L atm/K mol as our gas constant because it fits our units the best:

pV = nRTpV=nRT

n = (pV)/(RT) = ("2.3 atm" xx "1.00 L")/("0.08206 L atm/K mol" xx "300 K")n=pVRT=2.3 atm×1.00 L0.08206 L atm/K mol×300 K

n = "0.09 mol"n=0.09 mol

Now, we'll start gathering the values needed for the second equation to solve for the partial pressure of O_2O2.
We need to find the mole fraction of O_2O2 first—we know that "0.30 mol"0.30 mol of O_2O2 was added into the container and then "0.040 mol"0.040 mol of gas molecules leave after that.

Let's assume that an equal amount of N_2N2 and O_2O2 left; that, out of the "0.040 mol"0.040 mol, "0.020 mol"0.020 mol of N_2N2 left and "0.020 mol"0.020 mol of O_2O2 left.

This would leave us with "0.09 mol" - "0.020 mol" = "0.07 mol"0.09 mol0.020 mol=0.07 mol of N_2N2 gas and "0.30 mol" - "0.040 mol" = "0.26 mol"0.30 mol0.040 mol=0.26 mol of O_2O2 gas.

So, the mole fraction of O_2O2 gas would be:

x_(O_2) = (O_2)/(O_2 + N_2) = ("0.26 mol")/("0.26 mol" + "0.07 mol") = 0.8xO2=O2O2+N2=0.26 mol0.26 mol+0.07 mol=0.8

Then, we need to find the total pressure of both N_2N2 and O_2O2.
Since the container is still "1.00 L"1.00 L, (assuming it's) still at "300 K"300 K, and now has "0.26 mol" + "0.07 mol" = "0.3 mol"0.26 mol+0.07 mol=0.3 mol of gas in it, we can solve for pressure using the ideal gas law:

pV = nRTpV=nRT

p = (nRT)/v = ("0.3 mol" xx "0.08206 L atm/K mol" xx "300 K")/"1.00 L"p=nRTv=0.3 mol×0.08206 L atm/K mol×300 K1.00 L

p = "7 atm"p=7 atm

Now, we can use an expression of Dalton's law of partial pressures to solve for the partial pressure of O_2O2:

P_a = x_a xx P_"total"Pa=xa×Ptotal

P_(O_2) = x_(O_2) xx P_"total"PO2=xO2×Ptotal

P_a = 0.8 xx "7 atm" = "6 atm"Pa=0.8×7 atm=6 atm

Jun 16, 2018

p_text(O₂) = "6.6 atm"

Explanation:

Step 1. Calculate the moles of nitrogen

To answer this question, we'll need to use the Ideal Gas Law.

color(blue)(bar(ul(|color(white)(a/a)pV = nRTcolor(white)(a/a)|)))" "

We can rearrange this equation to get

n = (pV)/(RT)

In this problem,

pcolor(white)(l) = "2.3 atm"
V = "1.00 L"
R = "0.082 06 L·atm·K"^"-1""mol"^"-1"
T = "300 K"

n = (2.3 color(red)(cancel(color(black)("atm"))) × 1.00 color(red)(cancel(color(black)("L"))))/("0.082 06" color(red)(cancel(color(black)("L·atm·K"^"-1")))"mol"^"-1" × 300 color(red)(cancel(color(black)("K")))) = "0.0934 mol"

Step 2. Calculate the final moles of oxygen in the container

After adding oxygen, we have

"0.0934 mol N"_2 + "0.30 mol O"_2 = "0.3934 mol gas"

After allowing 0.040 mol of gas to leave, we have

"(0.3934 - 0.040) mol gas = 0.3534 mol gas"

" Moles of O"_2 = 0.3534 color(red)(cancel(color(black)("mol gas"))) × "0.30 mol O"_2/(0.3934 color(red)(cancel(color(black)("mol gas")))) = "0.270 mol O"_2

Step 3. Calculate the partial pressure of the oxygen

We can again use the Ideal Gas Law.

p = (nRT)/V

This time,

n = "0.270 mol"
R = "0.082 06 L·atm·K"^"-1""mol"^"-1"
T = "300 K"
V = "1.00 L"

p = (0.270 color(red)(cancel(color(black)("mol"))) × "0.082 06" color(red)(cancel(color(black)("L")))·"atm"·color(red)(cancel(color(black)("K"^"-1""mol"^"-1"))) × 300 color(red)(cancel(color(black)("K"))))/(1.00 color(red)(cancel(color(black)("L")))) = "6.6 atm"