Given
m_w->"Mass of water"="its volume"xx"densitymw→Mass of water=its volume×density
=25cm^3xx1g/(cm^3)=25g=25cm3×1gcm3=25g
t_w->"Initial temperature of water"=23^@Ctw→Initial temperature of water=23∘C
m_(Cd)->"Mass Cadmium"=65.5gmCd→Mass Cadmium=65.5g
t_(Cd)->"Initial temperature of Cd"=100^@CtCd→Initial temperature of Cd=100∘C
C_w->"Sp.heat capacity of water"=4.184J/(g^@C)Cw→Sp.heat capacity of water=4.184Jg∘C
C_(Cd)->"Sp.heat capacity of Cd"=0.2311J/(g^@C)CCd→Sp.heat capacity of Cd=0.2311Jg∘C
Let the final temperature of the system be t^@Ct∘C
So by calorimetric principle
"Heat lost by Cd" = "Heat gained by water"Heat lost by Cd=Heat gained by water
=>m_(Cd)xxC_(Cd)xx(t_(Cd)-t)= m_wxxC_wxx(t-t_w)⇒mCd×CCd×(tCd−t)=mw×Cw×(t−tw)
=>65.5xx0.2311xx(100-t)= 25xx4.184xx(t-23)⇒65.5×0.2311×(100−t)=25×4.184×(t−23)
=>(65.5xx0.2311)/(25xx4.184)xx(100-t)= (t-23)⇒65.5×0.231125×4.184×(100−t)=(t−23)
=>0.1447xx(100-t)= (t-23)⇒0.1447×(100−t)=(t−23)
=>14.47-0.1447t= (t-23)⇒14.47−0.1447t=(t−23)
=>1.1447t=37.47⇒1.1447t=37.47
=>t=37.47/1.1447~~32.73^@C⇒t=37.471.1447≈32.73∘C