Why can't I change the subscripts in a molecule when I balance a chemical reaction?

1 Answer
Dec 5, 2016

Because you change the integrity of the compound you're looking at.

For example:

6"HCl" + 2"Al"(s) -> 2"AlCl"_3 + 3"H"_2(g)6HCl+2Al(s)2AlCl3+3H2(g)

If you suddenly write 6"HCl"6HCl as 3"H"_2"Cl"_23H2Cl2, then what you've done is replace "HCl"HCl with a new molecule whose formula is "H"_2"Cl"_2H2Cl2, and this molecule may or may not exist. This one doesn't.

The new chemical formula of "H"_2"Cl"_2H2Cl2 literally tells you that there are two hydrogen atoms and two chlorine atoms in this hypothetical molecule, but "HCl"HCl only had one of each.

Likewise, 3"H"_2"Cl"_23H2Cl2 is also not the same as 3"H"_2 + 3"Cl"_23H2+3Cl2.