What total amount of heat input is required to heat "9 g"9 g of water from a liquid at 92^@ "C"92C to steam at 103^@ "C"103C?

1 Answer
Jul 27, 2017

q_(t ot) = 2._(067) xx 10^1qtot=2.067×101 "kJ"kJ

where subscripts are past the last significant digit (how sad!).


Here, we heat hot water to boil, and then heat it a bit further.

  • We assume that C_(P(l))CP(l), the heat capacity at constant pressure for liquid water, is still "4.184 J/g"^@ "C"4.184 J/gC at this TT and PP.
  • Since we are at constant atmospheric pressure, q = DeltaH. At constant temperature, the heat required is a constant dependent on the amount of substance available, and is related to the enthalpy of the vaporization process.

At the boiling point, q_(vap) = n_w DeltaH_(vap), where n_w is the mols of water at the boiling point and DeltaH_(vap) is "40.67 kJ/mol".

  • For steam, we have that C_(P(g)) = "1.996 J/g"^@ "C" near 100^@ "C".

The main steps are then:

underbrace("H"_2"O"(l))_(92^@ "C") stackrel(("Part 1"))stackrel(q = m_wC_(P(l))DeltaT" ")(->) stackrel(("Part 2"))(overbrace("boiling point")^(q = n_wDeltaH_(vap))) stackrel(("Part 3"))stackrel(q = m_wC_(P(g))DeltaT" ")(->) underbrace("H"_2"O"(g))_(103^@ "C")

That is, one heats to the boiling point, then boils, then heats further. We assume constant mass throughout (i.e. closed system).

1) Heating the liquid

q_1 = m_wC_(P(l))DeltaT

q_1 = "9 g" xx "4.184 J/g"^@ "C" xx (100^@ "C" - 92^@ "C")

= "301.248 J"

2) Vaporizing the liquid

q_2 = n_wDeltaH_(vap)

q_2 = (9 cancel("g H"_2"O") xx cancel"1 mol"/(18.015 cancel("g"))) xx ((40.67 cancel("kJ"))/cancel"mol" xx "1000 J"/cancel("1 kJ"))

= "20318.07 J"

3) Heating the steam

q_3 = m_wC_(P(g))DeltaT

q_3 = "9 g" xx "1.996 J/g"^@ "C" xx (103^@ "C" - 100^@ "C")

= "53.892 J"

Apparently, we only have one significant figure...?

color(blue)(q_(t ot)) = q_1 + q_2 + q_3

= "301.248 J" + "20318.07 J" + "53.892 J"

= "20673.21 J"

or about color(blue)("20.67 kJ"). Keep in mind that as-written, you have only allowed yourself one significant figure...