What total amount of heat input is required to heat "9 g"9 g of water from a liquid at 92^@ "C"92∘C to steam at 103^@ "C"103∘C?
1 Answer
q_(t ot) = 2._(067) xx 10^1qtot=2.067×101 "kJ"kJ where subscripts are past the last significant digit (how sad!).
Here, we heat hot water to boil, and then heat it a bit further.
- We assume that
C_(P(l))CP(l) , the heat capacity at constant pressure for liquid water, is still"4.184 J/g"^@ "C"4.184 J/g∘C at thisTT andPP . - Since we are at constant atmospheric pressure,
q = DeltaH . At constant temperature, the heat required is a constant dependent on the amount of substance available, and is related to the enthalpy of the vaporization process.
At the boiling point,
q_(vap) = n_w DeltaH_(vap) , wheren_w is the mols of water at the boiling point andDeltaH_(vap) is"40.67 kJ/mol" .
- For steam, we have that
C_(P(g)) = "1.996 J/g"^@ "C" near100^@ "C" .
The main steps are then:
underbrace("H"_2"O"(l))_(92^@ "C") stackrel(("Part 1"))stackrel(q = m_wC_(P(l))DeltaT" ")(->) stackrel(("Part 2"))(overbrace("boiling point")^(q = n_wDeltaH_(vap))) stackrel(("Part 3"))stackrel(q = m_wC_(P(g))DeltaT" ")(->) underbrace("H"_2"O"(g))_(103^@ "C")
That is, one heats to the boiling point, then boils, then heats further. We assume constant mass throughout (i.e. closed system).
q_1 = m_wC_(P(l))DeltaT
q_1 = "9 g" xx "4.184 J/g"^@ "C" xx (100^@ "C" - 92^@ "C")
= "301.248 J"
q_2 = n_wDeltaH_(vap)
q_2 = (9 cancel("g H"_2"O") xx cancel"1 mol"/(18.015 cancel("g"))) xx ((40.67 cancel("kJ"))/cancel"mol" xx "1000 J"/cancel("1 kJ"))
= "20318.07 J"
q_3 = m_wC_(P(g))DeltaT
q_3 = "9 g" xx "1.996 J/g"^@ "C" xx (103^@ "C" - 100^@ "C")
= "53.892 J"
Apparently, we only have one significant figure...?
color(blue)(q_(t ot)) = q_1 + q_2 + q_3
= "301.248 J" + "20318.07 J" + "53.892 J"
= "20673.21 J"
or about