Do kc have any unit?

1 Answer
Nov 22, 2017

Strictly...no......

Explanation:

K_"eq" is the so-called thermodynamic equilibrium constant....and thus for the reaction....

A+Brightleftharpoons C+D

K_"eq"=([C][D])/([A][B])....K_"eq" is properly dimensionless....

I grant that not all equilibria are set up like this, and conceivably we COULD have....

A+BrightleftharpoonsC

...the which, ostensibly, could have units. In these scenarios we use DIMENSIONLESS activities to report the concentration of [A], [B], and [C].

And why do we make all these specifications? Well, because of the "Gibbs Free Energy equation....", the which specifies that....

lnK_"eq"=-(DeltaG^@)/(RT)....and establishes the relationship of the thermodynamic equilibrium constant to the free energy, and of course we may only take "logs" of a dimensionless number....