Pascal's triangle up to the fifth term is:

You construct this by remembering that the first two rows are all 1. Then, you add the 1, 1 to get the 2 right below and between the two 1s from 1, 1. Basically you add number pairs together and put the result in between and below the number pair. 3 + 3 = 6, 4 + 6 = 10, etc.
Starting on the first row, the order is 0, and as you go down, it increases in integer steps. You can see that the third-order term is therefore 1, 3, 3, 1. To use it, you have:
(a + b)^3 = 1a^3b^0 + 3a^2b^1 + 3a^1b^2 + 1a^0b^3
(a - b)^3 = 1a^3b^0 - 3a^2b^1 + 3a^1b^2 - 1a^0b^3
Yours obviously has a subtraction sign; thus, you have, with a = 2x and b = 3y:
(2x - 3y)^3
= color(blue)(1)(2x)^color(green)(3)(3y)^color(green)(0) - color(blue)(3)(2x)^color(green)(2)(3y)^color(green)(1) + color(blue)(3)(2x)^color(green)(1)(3y)^color(green)(2) - color(blue)(1)(2x)^color(green)(0)(3y)^color(green)(3)
The triangle coefficients are highlighted in blue. Notice how since it's a cube of a difference, the signs alternate.
Also, notice in green that the order of the first term (2x) starts at 3 and ends at 0, while (3y) does the complete opposite, starting at 0 and ending at 3.
Simplifying it:
= (2x)^3 - 3(2x)^2(3y) + 3(2x)(3y)^2 - (3y)^3
= 8x^3 - (12x^2)(3y) + (6x)(9y^2) - (27y^3)
= color(blue)(8x^3 - 36x^2y + 54xy^2 - 27y^3)