What are some common mistakes students make with orbitals?

1 Answer
Jul 9, 2018

Well, I suppose it would be the following...


Two common mistakes would be:

  • Not knowing which orbitals physically exist AND why they do not.
  • Forgetting the difference between orbitals and subshells.

So, consider the following examples.

  1. Recall that the principal quantum number #n = 1, 2, 3, . . . # and the angular momentum quantum number #l = 0, 1, 2, . . . , ul(n-1)#.

    Therefore, it follows that if #n# is some integer, then #l# can be no greater than #n#, i.e. #1p#, #2d#, and #3f# orbitals do not exist, etc. because for these, it is NOT the case that #l < n#, while it must be.

  2. Or, we distinguish between the fact that if you have a set of #d# orbitals, it does not mean that #10# electrons can go into one orbital...

    But it DOES mean that you can have #10# electrons total in that subshell, as there can be #2# electrons per #d# orbital, of which there are #5#.