What is hybridization?

1 Answer

Hybridization is when two or more different types of orbitals combine with each other to form a new type of orbital in order to optimize bonding to other atoms.

Example: A Mg atom has only 2 electrons in its valence shell. In the ground state, they are paired in the 3s orbital, so this state cannot bond to other atoms. However, the 3s orbital can combine with one of the 3p orbitals to form two new sp orbitals. When one electron is in each orbital, then it is possible to form two equivalent bonds to 2 hydrogen atoms to form MgH2.

This is also the way that carbon can form 4 equivalent bonds. The 2s and 2p orbitals combine to form 4 equivalent sp3 hybridized orbitals. When bonded to 4 H atoms, you get methane.